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Matthew Cranswick, Ph.D.

Assistant Professor Inorganic Chemistry

Matthew Cranswick, Ph.D.
Contact Info
Office:
Chemistry (CHEM) 212

Bio

B.S. Chemistry, Oregon State University, 2001

Ph.D. Inorganic Chemistry (John H. Enemark and Dennis L. Lichtenberger), University of Arizona, 2008

NIH NRSA Postdoctoral Fellow (Lawrence Que, Jr), University of Minnesota – Twin Cities, 2008 - 2012

Research Interests

Research in the Cranswick lab focuses on (1) understanding the reaction mechanisms of unusual tungstoenzymes using small model complexes, (2) developing new ligand systems that reproduce key geometric and electronic properties of metalloenzymes, and (3) developing photocatalysts for small molecule activation.

Publications

Pre-independent Career

Khenkin, A. M.; Vedichi, M.; Shimon, L. J. W.; Cranswick, M. A.; Klein, J. E. M. N.; Que, L., Jr.; Neumann, R., “Hydrogen-Atom Transfer Oxidation with H2O2 Catalyzed by [FeII(1,2-bis(2,2'-bipyridyl-6-yl)ethane(H2O)2]2+: Likely Involvement of a (m-Hydroxo)(m-1,2-peroxo)diiron(III)

Intermediate” Israel J. Chem. 2017, 57 (10-11), 990-998

England, J.; Prakash, J.; Cranswick, M. A.; Mandal, D.; Guo, Y.; Münck, E; Shaik, S.; Que, L., Jr. “Oxoiron(IV) Complex of the Ethylene-Bridged Dialkylcyclam Ligand Me2EBC” Inorg. Chem. 2015, 54, 7828-7839

Makhlynets, O.; Oloo, W.; Moroz, Y.; Makarenko, I.; Palluccio, T.; Filatov, A.; Mueller, P.; Cranswick, M. A.; Que, L. Jr.; Rybak-Akimova, E. “H2O2 Activation with Biomimetic Non-haem Iron Complexes and AcOH: Connecting the g = 2.7 EPR Signal with a Visible Chromophore” Chem. Comm., 2014, 50(6), 645 – 648

Pap, J. S.; Cranswick, M. A.; Balogh-Hergovich, E.; Barath, G.; Giorgi, M.; Rohde, G. T.; Kaizer, J.; Speier, G.; Que, L., Jr. “An Iron(II)[1,3-bis(2′-pyridylimino)isoindoline] Complex as a Catalyst for Substrate Oxidation with H2O2 – Evidence for a Transient Peroxidodiiron(III) Species” Euro. J. Inorg. Chem., 2013, 22-23, 3858–3866

Cranswick, M. A.; Meier, K. K.; Shan, X.-P.; Stubna, A.; Kaizer, J.; Mehn, M. P.; Münck, E.; Que, L., Jr. “Protonation of a Peroxodiiron(III) Complex and Conversion to a Diiron(III/IV) Intermediate: Implications for Proton-assisted O–O Bond Cleavage in Nonheme Diiron Enzymes” Inorg. Chem., 2012, 51(19), 10417-10426

Wiebelhaus, N. J.; Cranswick, M. A.; Klein, E. L.; Lockett, L. T.; Lichtenberger, D. L. ; Enemark, J. H. “Metal-Sulfur Valence Orbital Interaction Energies in Metal–Dithiolene Complexes: Determination of Charge and Overlap Interaction Energies by Comparison of Core and Valence Ionization Energy Shifts“ Inorg. Chem., 2011, 50(21), 11021-11031

England, J.; Guo, Y.; Van Heuvelen, K. M.; Cranswick, M. A.; Rohde, G. T.; Bominaar, E.; Munck, E., Que, L., Jr. “A More Reactive Trigonal Bipyramidal High-Spin Oxoiron(IV) Complex with a cis-Labile Site”, J. Amer. Chem. Soc., 2011, 133(31),11880-11883

Li, F.; Meier, K. K.; Cranswick, M. A.; Chakrabarti, M.; Van Heuvelen, K. M.; Münck, E.; Que, L., Jr. “Characterization of a High-Spin Nonheme FeIII-OOH Intermediate and Its Conversion to an FeIV=O Complex.” J. Amer. Chem. Soc., 2011, 133(19), 7256-7259

England, J.; Farquhar, E. R.; Guo, Y.; Cranswick, M. A.; Ray, K.; Münck, E.; Que, L., Jr. “High-Potential Electrochemical Generation and Spectroscopic Characterization of a Trigonal Bipyramidal Tricationic Iron(IV) Cyanide Complex.” Inorg. Chem., 2011, 50, 2885-2896

Mukherjee, A.; Cranswick, M. A.; Chakrabarti, M.; Paine, T. K.; Fujisawa, K.; Münck, E.; Que, L., Jr. “Oxygen Activation at Mononuclear Nonheme Iron Centers: A Superoxo Perspective” Inorg. Chem.,2010, 49(8), 3618-3628; Forum on Dioxygen Activation and Reduction.

Cranswick, M. A; Gruhn, N. E.; Enemark, J. H.; Lichtenberger, D. L "Electronic Structure of the d¹ Bent-metallocene Cp2VCl2: A Photoelectron and Density Functional Study” J. Organomet. Chem. 2008, 693(8-9), 1621-1627; Invited Paper – F. Albert Cotton Memorial Issue.

Cranswick, M. A.; Winfield, K. R.; Gruhn, N. E.; Oorhles-Steele, O.; Schenk, W. A.; Burzaff, N.; Lichtenberger, D. L. “Energetic and Geometric Effects on M-S dπ-pπ Orbital Interactions of (η5-C5H5)Fe(CO)2SCH3 and (η5-C5H5)Re(NO)(PR3)SCH3 [PR3 = PiPr3, PPh3].” Inorg. Chim. Acta, 2008, 361(4), 1122-1133; Invited Paper – Protagonists in Chemistry: Professor Edward I. Solomon.

Cranswick, M. A; Dawson, A.; Cooney, J. J. A.; Gruhn, N. E.; Lichtenberger, D. L.; Enemark, J. H. “Photoelectron Spectroscopy and Electronic Structure Calculations of d1 Vanadocene Compounds with Chelated Dithiolate Ligands: Implications for Pyranopterin Mo/W Enzymes.” Inorg. Chem. 2007, 46, 10639-10646

Cooney, J. J. A.; Cranswick, M. A.; Gruhn, N. E.; Joshi, H. K.; Enemark, J. H. “Electronic structure of bent titanocene complexes with chelated dithiolate ligands.” Inorg. Chem., 2004, 43(25), 8110-8118.

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